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An anionic metal–organic framework based on angular tetracarboxylic acid and a mononuclear copper ion for selective gas adsorption

Jingjing JiaoCollege of Chemistry and Life SciencesHuimin LiuCollege of Chemistry and Life SciencesFengli ChenCollege of Chemistry and Life SciencesDongjie BaiCollege of Chemistry and Life SciencesShunshun XiongChina Academy of Engineering PhysicsYabing HeChina

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A rare example of a MOF, <bold>ZJNU-55</bold>, based on mononuclear Cu(COO)<sub>4</sub> and an angular diisophthalate linker with a novel topological structure exhibiting selective adsorption of C<sub>2</sub>H<sub>2</sub> and CO<sub>2</sub> from CH<sub>4</sub> at room temperature was presented.

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