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Short-Range Slowdown of Water Solvation Dynamics around SO42- - Mg2+ Ion Pairs

Achintya KunduMax-Born-Institut für Nichtlineare Optik und Kurzzeitspektroskopie, Berlin 12489, GermanyShavkat MamatkulovInstitute of material science the Uzbekistan AS, Tashkent, UzbekistanFlorian N. BrünigFachbereich Physik, Freie Universitaet Berlin, 14195 Berlin, GermanyDouwe Jan BonthuisInstitute of Theoretical and Computational Physics Graz University of Technology, 8010 Graz, AustriaRoland R. NetzFachbereich Physik, Freie Universitaet Berlin, 14195 Berlin, GermanyThomas ElsaesserMax-Born-Institut für Nichtlineare Optik und Kurzzeitspektroskopie, Berlin 12489, GermanyBenjamin P. FingerhutMax-Born-Institut für Nichtlineare Optik und Kurzzeitspektroskopie, Berlin 12489, Germany

The International Conference on Ultrafast Phenomena (UP) 2022conference2022en

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Annotatsiya

2D-IR spectroscopy in the fingerprint region of SO 4 2- ions in water reveals a counterion specific slowdown of solvation dynamics. Hydration structures of solvent shared SO 4 2- - Mg 2+ ion pairs are identified as the molecular origin.

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Mavzular

Spectroscopy and Quantum Chemical Studies Molecular spectroscopy and chirality Advanced Chemical Physics Studies

Identifikatorlar

DOI: 10.1364/up.2022.f2a.2

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