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Adsorption activity of pillared clays with respect to vapors of organic adsorbates

Nozim MamatalievInstitute of General and Inorganic Chemistry Academy of Sciences of the Republic of Uzbekistan Tashkent, 77a, Mirzo Ulugbek str., 100170 UzbekistanAziza AbdikamalovaInstitute of General and Inorganic Chemistry Academy of Sciences of the Republic of Uzbekistan Tashkent, 77a, Mirzo Ulugbek str., 100170 UzbekistanIzzat EshmetovNational University of Uzbekistan named after M. Ulugbek Tashkent, 4, Universitetskaya str., 100174 UzbekistanAlisher KalbaevInstitute of General and Inorganic Chemistry Academy of Sciences of the Republic of Uzbekistan Tashkent, 77a, Mirzo Ulugbek str., 100170 Uzbekistan
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Cr and Cr + Al intercalated montmorillonites and their adsorption activity with respect to various adsorbates have been studied.The results of X-ray phase analysis showed that for the Logon bentonite sample, the value of the basal reflection d 001 is about 12.3 Å.For Cr and Cr + Al intercalated materials, a shift of the d 001 reflection towards a smaller angle is observed, which indicates an increase in the basal distance and intercalation efficiency and its values are 17.5 and 19.8 Å, respectively.A structural change in montmorillonite as a result of pillaring leads to an increase in its textural characteristics and adsorption activity with respect to polar and nonpolar molecules.The textural characteristics of mixed chromium-aluminum intercalated montmorillonite, calculated from the adsorption of nitrogen, hexane and toluene, are much higher compared to the characteristics of a sample of chromium intercalated bentonite.

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