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Synthesis, crystal structure and Hirshfeld surface analysis of a coordination compound of cadmium nitrate with 2-aminobenzoxazole

Surayyo RazzoqovaNational University of Uzbekistan named after Mirzo Ulugbek 4 University St Tashkent 100174 UzbekistanYodgor RuzimovKhorezm Mamun branch of Uzbekistan Academy of Sciences, 1, Markaz St., Khiva, 220900, UzbekistanAkobir ToshovNational University of Uzbekistan named after Mirzo Ulugbek 4 University St Tashkent 100174 UzbekistanBatirbay TorambetovNational University of Uzbekistan named after Mirzo Ulugbek 4 University St Tashkent 100174 UzbekistanAziz B. IbragimovInstitute of General and Inorganic Chemistry, Academy of Sciences of Uzbekistan, M. Ulugbek Str 77a, Tashkent 100170, UzbekistanJamshid AshurovInstitute of Bioorganic Chemistry, Academy of Sciences of Uzbekistan, M. Ulugbek, St, 83, Tashkent, 100125, UzbekistanShakhnoza KadirovaNational University of Uzbekistan named after Mirzo Ulugbek 4 University St Tashkent 100174 Uzbekistan

Acta Crystallographica Section E Crystallographic Communicationsjournal2025en

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Annotatsiya

A coordination complex of cadmium nitrate [Cd(NO 3 ) 2 ] with 2-aminobenzaxole (2AB; C 7 H 6 N 2 O), namely, tetrakis(2-aminobenzoxazole-κ N 1 )bis(nitrato-κ O )cadmium(II), [Cd(NO 3 ) 2 (2AB) 4 ], has been synthesized from ethanol solutions of Cd(NO 3 ) 2 ·H 2 O and 2AB. The asymmetric unit comprises half a molecule of [Cd(NO 3 ) 2 (2AB) 4 ], with the Cd II atom positioned on a twofold rotation axis. In the completed molecular complex, four 2AB ligands and two nitrate anions each coordinate monodentately to the Cd II atom, leading to a distorted octahedral coordination environment. The crystal structure of [Cd(NO 3 ) 2 (2AB) 4 ] exhibits several N—H...O interactions, resulting in the formation of a layered assembly parallel to (001). Hishfeld surface analysis was used to quantify the intermolecular interactions.

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Crystal structures of chemical compounds Nonlinear Optical Materials Research Metal complexes synthesis and properties

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DOI: 10.1107/s2056989025004049

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