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Interfacial orbital asymmetry enables redox reactions at the MXene–water interface

Changzhi ChenState Key Laboratory of Radiation Medicine and Protection, School of Radiation Medicine and Protection, Collaborative Innovation Center of Radiological Medicine of Jiangsu Higher Education Institutions, Soochow University, Suzhou 215123, ChinaK. T. NormurodovaDepartment of Biotechnology and Microbiology, Faculty of Biology and Ecology, National University of Uzbekistan named after Mirzo Ulugbek, 100174 Tashkent, UzbekistanNurad BОZОRОVDepartment of Biotechnology and Microbiology, Faculty of Biology and Ecology, National University of Uzbekistan named after Mirzo Ulugbek, 100174 Tashkent, UzbekistanAbid Aslam MaanDepartment of Food Engineering, National Institute of Food Science and Technology, University of Agriculture, Faisalabad, 38000, PakistanDzeufiet Djomeni Paul DésiréDepartment of Animal Biology and Physiology, Laboratory of Animal Physiology, Faculty of Science, University of Yaounde 1, P.O. Box 812, Yaounde, CameroonMeng GaoState Key Laboratory of Radiation Medicine and Protection, School of Radiation Medicine and Protection, Collaborative Innovation Center of Radiological Medicine of Jiangsu Higher Education Institutions, Soochow University, Suzhou 215123, ChinaRuibin LiState Key Laboratory of Radiation Medicine and Protection, School of Radiation Medicine and Protection, Collaborative Innovation Center of Radiological Medicine of Jiangsu Higher Education Institutions, Soochow University, Suzhou 215123, China
2026en

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H. Remarkably, the interfacial reaction proceeds efficiently in aqueous solution at room temperature, affording a high yield (95%) and enabling spontaneous phase separation of the product, which simplifies downstream purification. This work introduces a nano-enabled and mechanistically distinct redox pathway, highlighting the potential of asymmetric orbital-driven interfacial reactions for green synthetic chemistry.

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