Maqola

Synthesis, structure and computational study of diacetatobis(2-amino-6-fluoro-1,3-benzothiazole-κ N 3 )zinc(II)

Dilshoda AmanovaTermez Branch of Tashkent State Medical University, 64 Islom Karimov Street, Termiz 132000, UzbekistanZubaydabegim RADJABOVANational University of Uzbekistan named after Mirzo Ulugbek, University Street, 4, Tashkent 100174, UzbekistanSardor MurodovNational University of Uzbekistan named after Mirzo Ulugbek, University Street, 4, Tashkent 100174, UzbekistanSevinch ErkinboyevaNational University of Uzbekistan named after Mirzo Ulugbek, University Street, 4, Tashkent 100174, UzbekistanOdil ChorievInstitute of Bioorganic Chemistry, Academy of Sciences of Uzbekistan, Mirzo, Ulugbek Street 83, Tashkent 100125, UzbekistanJamshid AshurovInstitute of Bioorganic Chemistry, Academy of Sciences of Uzbekistan, Mirzo, Ulugbek Street 83, Tashkent 100125, UzbekistanShahlo DaminovaNational University of Uzbekistan named after Mirzo Ulugbek, University Street, 4, Tashkent 100174, Uzbekistan

2026

Ochiq kirishOltin

Litsenziya: cc-by

Manbada oʻqishdoi.org(yangi oynada ochiladi)

ABI

Annotatsiya

In the title zinc(II) complex, [Zn(C 2 H 3 O 2 ) 2 (C 7 H 5 FN 2 S) 2 ], the Zn II atom adopts a tetrahedral coordination geometry (τ 4 = 0.96), defined by two nitrogen atoms from two neutral 2-amino-6-fluoro-1,3-benzothiazole ligands and two oxygen atoms from two monodentately coordinated acetate anions. The crystal packing is governed by classical N—H...O hydrogen bonds, which generate one-dimensional chains extending along the [011] direction. These chains are further reinforced by bifurcated N—H...(O,F) hydrogen bonds together with C—H...π, O...π, and offset π–π interactions, resulting in a robust three-dimensional supramolecular framework. Hirshfeld surface analysis reveals that H...H (31.5%), C...H/H...C (16.3%), O...H/H...O (13.0%), F...H/H...F (12.9%), and S...H/H...S (10.2%) contacts make the largest contributions to the crystal packing, while a void analysis confirms the efficient packing of the molecules within the crystal.

Hali tarjima qilinmagan

Identifikatorlar

DOI: 10.1107/s2056989026009163

Iqtiboslar va manbalar

0 ta iqtibos0 ta foydalanilgan manba