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Theoretical Description for the Electrochemical Determination of Two Aryloxyphenoxypropionate Herbicides in Soy Products

Tetiana V. MorozovaState Scientific Institution “Institute of Ecological Restoration and Development of Ukraine”, Environment Remediation Section, Mytropolite Vasyl Lypkivsky Str. 35, 01001 Kyiv, UkraineVolodymyr TkachUniversity of Trás-os-Montes and Alto Douro, Quinta de Prados, 5001-801, Folhadela, Vila Real, PortugalМарта Василівна КушнірChernivtsi National University, 58001, Kotsiubynsky Str. 12, Chernivtsi, UkraineLyudmyla V. RomanivChernivtsi National University, 58001, Kotsiubynsky Str. 12, Chernivtsi, UkraineSílvio C. de OliveiraInstitute of Chemistry. Federal University of Mato Grosso do Sul, 79074 – 460, Av. Sen. Felinto Müller, 1555, Vila Ipiranga, Campo Grande, MS, BrazilYana G. IvanushkoBukovinian State Medical University, 58001, Teatralna Sq., 9, Chernivtsi, UkrainePetro Ivanonych YagodynetsChernivtsi National University, 58001, Kotsiubynsky Str. 12, Chernivtsi, UkrainAdriano Olímpio da SilvaV. M. OdyntsovaZaporizhzhia State Medical University, 69600, Mayakovsky Ave. 24, Zaporizhzhia, UkraineM.P. KraskoZaporizhzhia State Medical University, 69600, Mayakovsky Ave. 24, Zaporizhzhia, UkraineОлена Олександрівна ВасильєваKyiv National University of Trade and Economics, 02156, Kyoto Str. 21, Kyiv, UkraineО. В. ГрабовськаKyiv National University of Trade and Economics, 02156, Kyoto Str. 21, Kyiv, UkraineDilfuza M. MusayevaAbu Ali Ibn Sino Bukhara State Medical Institute, 705018, Navoi Str., 1, Bukhara, UzbekistanBakhodirjon SamadovAbu Ali Ibn Sino Bukhara State Medical Institute, 705018, Navoi Str., 1, Bukhara, UzbekistanL. N. NiyazovAbu Ali Ibn Sino Bukhara State Medical Institute, 705018, Navoi Str., 1, Bukhara, UzbekistanMaria João MonteiroUniversity of Trás-os-Montes and Alto Douro, Quinta de Prados, 5001-801, Folhadela, Vila Real, PortugalJarem Raul GarciaUniversity of Trás-os-Montes and Alto Douro, Quinta de Prados, 5001-801, Folhadela, Vila Real, PortugalJ.I. MartinsState University of Ponta Grossa, Uvaranas Campus, Av. Gal. Carlos Cavalcanti, 4748, 84030-900, Ponta Grossa, PR, BrazilZholt O. KormoshEngineering Faculty of the University of Porto, 4200-465, Rua Dr. Roberto Frias, s/n, Porto, PortugalА. В. ГрековаVolyn National University, 43000, Voli Ave., 13, Lutsk, UkraineIanina F. BurdinaVolyn National University, 43000, Voli Ave., 13, Lutsk, UkraineІнеса Макарівна ХмелярOdesa National Medical University, 65000, Valikhovsky Ln. 2, Odesa, UkraineLesya O. KushnirOdesa National Medical University, 65000, Valikhovsky Ln. 2, Odesa, UkraineGalyna PochenchukChernivtsi National University, 58001, Kotsiubynsky Str. 12, Chernivtsi, Ukraine

2026

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Annotatsiya

In this work, the possibility of the electrochemical determination of two aryloxyphenoxypropionate pesticides in soy products, assisted by copper sulfide nanoparticles, paired with in situ trivalent copper sulfohydroxide. Oxidation scenarios, including N-oxidation, intramolecular heterocyclization, and electropolymerization, are included in the model. The model is analyzed using linear stability theory and bifurcation analysis. It confirms that the steady-state stability is easily obtained and maintained so that the electrochemical process may be efficient for either pesticide quantification or removal by their immobilization in the polymer phase, despite the enhanced probability of electrochemical oscillations.

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DOI: 10.33263/lianbs153.105

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