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White light emission from a single organic molecule with dual phosphorescence at room temperature

Zikai HeSchool of Science, Harbin Institute of Technology Shenzhen, HIT Campus of University Town of Shenzhen, Shenzhen, 518055, ChinaWeijun ZhaoHKUST Shenzhen Research Institute, No. 9 Yuexing 1st RD, South Area, Hi-tech Park Nanshan, Shenzhen, 518000, ChinaJacky W. Y. LamInstitute of Molecular Functional MaterialsQian PengInstitute of ChemistryHuili MaKey Laboratory of Organic OptoElectronics and Molecular Engineering, Department of Chemistry, Tsinghua University, Beijing, 100084, ChinaGuodong LiangDSAP, PCFM and GDHPPC Lab, School of Materials Science and Engineering, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou, 510275, ChinaZhigang ShuaiKey Laboratory of Organic OptoElectronics and Molecular Engineering, Department of Chemistry, Tsinghua University, Beijing, 100084, ChinaBen Zhong TangHKUST Shenzhen Research Institute, No. 9 Yuexing 1st RD, South Area, Hi-tech Park Nanshan, Shenzhen, 518000, China. [email protected]

2017en

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Litsenziya: cc-by

ABI

Annotatsiya

Abstract The development of single molecule white light emitters is extremely challenging for pure phosphorescent metal-free system at room temperature. Here we report a single pure organic phosphor, namely 4-chlorobenzoyldibenzothiophene, emitting white room temperature phosphorescence with Commission Internationale de l’Éclair-age coordinates of (0.33, 0.35). Experimental and theoretical investigations reveal that the white light emission is emerged from dual phosphorescence, which emit from the first and second excited triplet states. We also demonstrate the validity of the strategy to achieve metal-free pure phosphorescent single molecule white light emitters by intrasystem mixing dual room temperature phosphorescence arising from the low- and high-lying triplet states.

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DOI: 10.1038/s41467-017-00362-5

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