Renewable Hydrogen from Ethanol by Autothermal Reforming
Gregg A. DelugaDepartment of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis MN 55455, USAJ. R. SalgeDepartment of Chemical Engineering, University of Patras, GR-26500 Patras GreeceL.D. SchmidtDepartment of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis MN 55455, USAXenophon E. VerykiosDepartment of Chemical Engineering, University of Patras, GR-26500 Patras Greece
2004en
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Ethanol and ethanol-water mixtures were converted directly into H2 with approximately 100% selectivity and >95% conversion by catalytic partial oxidation, with a residence time on rhodium-ceria catalysts of <10 milliseconds. Rapid vaporization and mixing with air with an automotive fuel injector were performed at temperatures sufficiently low and times sufficiently fast that homogeneous reactions producing carbon, acetaldehyde, ethylene, and total combustion products can be minimized. This process has great potential for low-cost H2 generation in fuel cells for small portable applications where liquid fuel storage is essential and where systems must be small, simple, and robust.
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