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Reversible Martensitic Phase Transition in Yttrium-Stabilized ZrO2 Nanopowders by Adsorption of Water

E. B. AsgerovNational Nuclear Research Center CJSC, Baku AZ1073, AzerbaijanA. I. BeskrovnyyJoint Institute for Nuclear Research, 141980 Dubna, RussiaNelya V. DoroshkevichDonetsk National Vasyl Stus University, 21021 Vinnitsa, UkraineCarmen MîţăFaculty of Physics, Alexandru Ioan Cuza University of Iasi, Bulevardul Carol I nr. 11, 700506 Iași, RomaniaDiana MardareFaculty of Physics, Alexandru Ioan Cuza University of Iasi, Bulevardul Carol I nr. 11, 700506 Iași, RomaniaDan ChiceaResearch Center for Complex Physical Systems, Faculty of Sciences, “Lucian Blaga” University of Sibiu, Dr. Ion Ratiu str. no. 5–7, 550012 Sibiu, RomaniaMihaela D. LazărNational Institute for Research and Development of Isotopic and Molecular Technologies, 400293 Cluj-Napoca, RomaniaAlisa A. TatarinovaJoint Institute for Nuclear Research, 141980 Dubna, RussiaSergiy LyubchykResearch Centre in Industrial Engineering Management and Sustainability, Lusófona University, Campo Grande, 376, 1749-024 Lisboa, PortugalAndriy LyubchykREQUIMTE, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, Quina de Torre, 2829-516 Caparica, PortugalAndriy I. LyubchykNanotechcenter LLC, Krzhizhanovsky str., 3, 03680 Kyiv, UkraineAlexander DoroshkevichJoint Institute for Nuclear Research, 141980 Dubna, Russia

2022en

ABI

Annotatsiya

-nanoparticles. Three basic methods were used to determine the phase transition: neutron diffraction, Raman microspectroscopic scanning, and X-ray diffraction. The fact of reversible phase-structural β → α transformation and the simultaneous presence of two polymorphic structural modifications (β is the phase of the tetragonal syngony and α of monoclinic syngony in nanosized particles (9 nm)) under normal physical conditions was established by these methods. An assumption was made regarding the connection of the physical mechanism of transformation of the extremely nonequilibrium surface of nanoparticles with electronic exchange of the material of the near-surface layer of nanoparticles with the adsorption layer through donor-acceptor interaction. The principal possibility of creating direct-acting hydroelectric converters based on nanoscale YSZ (Yttria-Stabilized Zirconia) systems due to the reversible character of the considered effect was shown.

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DOI: 10.3390/nano12030435

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