A host–guest inclusion compound for reversible switching of quadratic nonlinear optical properties
Chengmin JiChinese Academy of SciencesZhihua SunFuzhouShuquan ZhangFujian Institute of Research on the Structure of MatterSangen ZhaoChinese Academy of SciencesTianliang ChenChinese Academy of SciencesYuan‐Yuan TangChinese Academy of SciencesJunhua LuoFuzhou
2014en
ABI
Annotatsiya
A host-guest inclusion compound [(DPA)(18-crown-6)]ClO4 (DPA = dipropylamine) undergoes a reversible phase transition at 214 K, which enables it to switch the NLO response between SHG-ON and SHG-OFF states associated with the order-disorder transition of the guest DPA cations and a slight tilting of the host 18-crown-6 molecules.
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