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Phase composition and dissociation processes in metal–ammonia solid solution

I. S. ShchetkinPhysicotechnical Institute of Low Temperatures, Academy of Sciences of the Ukrainian SSRG. I. TarasenkoPhysicotechnical Institute of Low Temperatures, Academy of Sciences of the Ukrainian SSRE. A. OsikaPhysicotechnical Institute of Low Temperatures, Academy of Sciences of the Ukrainian SSRG. M. TsoĭPhysicotechnical Institute of Low Temperatures, Academy of Sciences of the Ukrainian SSRI. M. DmitrenkoPhysicotechnical Institute of Low Temperatures, Academy of Sciences of the Ukrainian SSR

Soviet Journal of Low Temperature Physicsjournal1976en

ABI

Annotatsiya

Sodium–ammonia solutions with various sodium concentrations were examined thermographically over the 77−200°K temperature range. The results indicate a heterogeneous state of frozen sodium–ammonia solutions. An analysis of the conditions under which these solutions are quenched confirms the feasibility of precipitating a structurally free phase richer in metal. The presence of such a metallized phase determines the anomalous physical properties of metal–ammonia solid solutions.

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Mavzular

Ammonia Synthesis and Nitrogen Reduction

Identifikatorlar

DOI: 10.1063/10.0029375

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