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Mechanism of phase transition in monoclinic potassium–dysprosium tungstenate

I. V. SkorobogatovaPhysicotechnical Institute of Low Temperatures, Academy of Sciences of the Ukrainian SSR, Khar’kovE. M. SavchenkoPhysicotechnical Institute of Low Temperatures, Academy of Sciences of the Ukrainian SSR, Khar’kov
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The observed anomaly in the temperature dependence of the position of lines in the absorption spectrum of KDy(WO4)2 is explained by the occurrence of a CJTE-type (cooperative Jahn–Teller effect) phase transition. It is also demonstrated that only Ci1 can be the space group of a KDy(WO4)2 crystal at temperature below 10°K.

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