Clusters of exchange-coupled oxygen molecules in solidified-gas matrices
V. S. OstrovskiǐPhysicotechnical Institute of Low Temperatures, Academy of Sciences of the Ukrainian SSR, Khar’kovV. V. SumarokovPhysicotechnical Institute of Low Temperatures, Academy of Sciences of the Ukrainian SSR, Khar’kovYu. A. FreĭmanPhysicotechnical Institute of Low Temperatures, Academy of Sciences of the Ukrainian SSR, Khar’kov
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The energy spectrum of an exchange-coupled pair of oxygen molecules with arbitrary orientation of the axes of the molecules as well as the contribution of paired clusters to the thermodynamics of solid solutions of solidified gases with oxygen are calculated. It is shown that the study of the anomalies of the thermodynamic properties of these solutions can be used to study the exchange interaction of O2 molecules.
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