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Magnetic properties of cobalt orotate

A. I. ZvyaginPhysicotechnical Institute of Low Temperatures, Academy of Sciences of the Ukrainian SSR, KharkovA. I. KaplienkoPhysicotechnical Institute of Low Temperatures, Academy of Sciences of the Ukrainian SSR, KharkovM. I. KobetsPhysicotechnical Institute of Low Temperatures, Academy of Sciences of the Ukrainian SSR, KharkovV. G. MitkevichPhysicotechnical Institute of Low Temperatures, Academy of Sciences of the Ukrainian SSR, KharkovA. A. StepanovPhysicotechnical Institute of Low Temperatures, Academy of Sciences of the Ukrainian SSR, KharkovS. M. TretyakPhysicotechnical Institute of Low Temperatures, Academy of Sciences of the Ukrainian SSR, KharkovE. N. KhatskoPhysicotechnical Institute of Low Temperatures, Academy of Sciences of the Ukrainian SSR, Kharkov
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The magnetic properties of cobalt orotate single crystals are investigated and the crystallographic structure of the material is decoded. It is found that in the temperature region 2–20 K, cobalt orotate is a paramagnet with a considerable anisotropy of susceptibility. The values of energies of six Kramers doublets corresponding to the lower level of the Co ion are determined by using the crystal field model together with the crystal field constants corresponding to the experimental set of g-factors.

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