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Appearance of molecular hydrogen in the ultraviolet spectra of diamond-like carbon

B. R. NamozovA. F. Ioffe Physicotechnical Institute, Russian Academy of Sciences, St. PetersburgÉ. A. SmorgonskayaA. F. Ioffe Physicotechnical Institute, Russian Academy of Sciences, St. PetersburgM. P. KorobkovA. F. Ioffe Physicotechnical Institute, Russian Academy of Sciences, St. PetersburgV. I. Ivanov-OmskiĭA. F. Ioffe Physicotechnical Institute, Russian Academy of Sciences, St. Petersburg
Technical Physics Lettersjournal1997en
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Ultraviolet Raman scattering is used to study the state of hydrogen in diamond-like α-C:H. Scattering lines are observed corresponding to transitions between the rotational states of the hydrogen molecule. The interaction with the α-C:H matrix increases the internuclear distance and perturbs the electronic-vibrational terms of the H2 molecule, so that resonance Raman scattering can be observed, excited by 10.04 eV photons.

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