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Possible mechanisms of charge separation during exiton decay in the polymer matrices of third-generation solar cells

Б. Л. ОксенгендлерInstitute for the Chemistry and Physics of Polymers, Uzbekistan Academy of Sciences, Tashkent, 100128, UzbekistanOksana IsmailovaInstitute of Ion-Plasma and Laser Technologies, Uzbekistan Academy of Sciences, Tashkent, 100128, UzbekistanM. B. MarasulovInstitute for the Chemistry and Physics of Polymers, Uzbekistan Academy of Sciences, Tashkent, 100128, UzbekistanN. N. TuraevaWebster University, Webster Groves, MO, 63119, USAИ. Н. НургалиевInstitute for the Chemistry and Physics of Polymers, Uzbekistan Academy of Sciences, Tashkent, 100128, Uzbekistan
Applied Solar Energyjournal2014en
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An important stage in the functioning of third-generation solar cells based on polymers is considered: the dissociation of exitons generated by solar light and the separation of the resulting electrons and holes. Various molecular mechanisms for the formation of free charge carriers are studied by means of quantum mechanics and statistical physics. Some processes are associated with polymer matrices; others with systems typical of ideal neat matrices.

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