Crystal and molecular structure of β-(N-benzoxazoline-2-thione) propionic acid and its salts
Jamshid AshurovSadykov Institute of Bioorganic Chemistry, Academy of Sciences of the Republic of Uzbekistan, Tashkent, Republic of UzbekistanB. TashkhodjaevYunusov Institute of the Chemistry of Plant Substances, Academy of Sciences of the Republic of Uzbekistan, Tashkent, Republic of UzbekistanL. Yu. IzotovaSadykov Institute of Bioorganic Chemistry, Academy of Sciences of the Republic of Uzbekistan, Tashkent, Republic of UzbekistanM. I. OlimovaYunusov Institute of the Chemistry of Plant Substances, Academy of Sciences of the Republic of Uzbekistan, Tashkent, Republic of UzbekistanБ. Т. ИбрагимовSadykov Institute of Bioorganic Chemistry, Academy of Sciences of the Republic of Uzbekistan, Tashkent, Republic of Uzbekistan
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The crystal and molecular structures of β-(N-benzoxazoline-2-thione)propionic acid, its monoethanolammonium (NН2(CH2)2OH) and ethylenediammonium (NН2(CH2)2NH2) salts are studied. In the salts the monoethyleneamine amine group participates in the deprotonation of one ethylenediamine–two β-(N-benzthiazolin-2-one)propionic acid molecules. The geometry of the molecules and intermolecular hydrogen and donor-acceptor bonds in crystals are analyzed. In the crystal structures weak interactions form a two-dimensional layer whose thickness corresponds to unit cell sizes.
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