Catalytic Reaction with Benzoic Acid Phenylacetylene in the Presence of Complex Catalysts
A.B. ParmanovDepartment of General and Oil-Gas Chemistry, National University of Uzbekistan, UzbekistanSuvankul E. NurmanovDepartment of General and Oil-Gas Chemistry, National University of Uzbekistan, UzbekistanMirjalol E. ZiyadullaevDepartment of Chemistry, Chirchik State Pedagogical University, UzbekistanNavro’za U. BekboyevaDepartment of General and Oil-Gas Chemistry, National University of Uzbekistan, UzbekistanNizombek D. XolmuhammedovDepartment of Basic Organic Synthesis Technology, Tashkent Institute of Chemical Technology, UzbekistanSh.Sh. TursunovDepartment of General and Oil-Gas Chemistry, National University of Uzbekistan, Uzbekistan
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In this work, we studied the processes of vinyl ester formation by the addition of benzoic acid to phenylacetylene in the presence of complex catalysts of diacetate-di (2-amino-5-methylthio-1,3,4-thiadiazolo) cobalt(II) ([Co(C3H5N3S2)2(CH3COO)2] and tetrakis(2-amino-5-ethylthio-1,3,4-thiadiazole)-zinc(II) dinitrate ([Zn(C4H7S2)4](NO3)2): 1-phenylvinyl benzoate and anti-Markovnikov coupling product - styryl benzoate were obtained. The effect of the nature of solvents on the yields of products in the presence of the [Zn(C4H7S2)4](NO3)2 complex catalyst was studied. The structure of the synthesized vinyl esters was proved by IR, 1H NMR, 13C NMR spectroscopies.
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