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Enhanced redox kinetics for hydrogen peroxide photosynthesis at high-concentration by encapsulating porphyrin metal–organic frameworks with phenolic resin

Houwei HeKey Laboratory of Green and Precise Synthetic Chemistry and Applications, Ministry of Education, Anhui Province Key Laboratory of Pollutant Sensitive Materials and Environmental Remediation, School of Physics and Electronic Information, Huaibei Normal University, Huaibei 235000, Anhui, P. R. ChinaZhongliao WangKey Laboratory of Green and Precise Synthetic Chemistry and Applications, Ministry of Education, Anhui Province Key Laboratory of Pollutant Sensitive Materials and Environmental Remediation, School of Physics and Electronic Information, Huaibei Normal University, Huaibei 235000, Anhui, P. R. ChinaJinfeng ZhangKey Laboratory of Green and Precise Synthetic Chemistry and Applications, Ministry of Education, Anhui Province Key Laboratory of Pollutant Sensitive Materials and Environmental Remediation, School of Physics and Electronic Information, Huaibei Normal University, Huaibei 235000, Anhui, P. R. ChinaShavkat MamatkulovDepartment of Natural-Mathematical Science, Turin Polytechnic University in Tashkent, Tashkent 100095, UzbekistanOlim RuzimuradovDepartment of Natural-Mathematical Science, Turin Polytechnic University in Tashkent, Tashkent 100095, UzbekistanKai DaiKey Laboratory of Green and Precise Synthetic Chemistry and Applications, Ministry of Education, Anhui Province Key Laboratory of Pollutant Sensitive Materials and Environmental Remediation, School of Physics and Electronic Information, Huaibei Normal University, Huaibei 235000, Anhui, P. R. ChinaJingxiang LowSchool of Physical Science and Technology, Tiangong University, Tianjin 300387, P. R. ChinaYue LiSchool of Physical Science and Technology, Tiangong University, Tianjin 300387, P. R. China
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A highly interface-adapted all-organic step-scheme photocatalyst based on porphyrin metal–organic frameworks and phenolic resin is constructed, which shows enhanced charge transfer dynamics and reduced O 2 activation energy barrier.

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