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Optical Absorption and Luminescence Spectra of Terbium Gallium Garnet TbGaG and Terbium Aluminum Garnet TbAlG

Nosirjon S. BozorovDepartment of Physics and Astronomy, Kokand State University, Kokand 713000, UzbekistanIsmailjan M. KokanbayevDepartment of Physics and Astronomy, Kokand State University, Kokand 713000, UzbekistanAkmaljon M. MadalievDepartment of Physics and Astronomy, Kokand State University, Kokand 713000, UzbekistanMavzurjon Xurshidboyevich Qo’chqorovDepartment of Physics and Astronomy, Kokand State University, Kokand 713000, UzbekistanMuxtarjan MeliboevDepartment of Physics and Astronomy, Kokand State University, Kokand 713000, UzbekistanKobiljon K. KurbonalievDepartment of Physics and Astronomy, Kokand State University, Kokand 713000, UzbekistanRavshan Rustamovich SultonovDepartment of Physics and Astronomy, Kokand State University, Kokand 713000, UzbekistanKh. F. MakhmudovIoffe Institute, Saint Petersburg 194021, RussiaFeruza O. DadaboyevaDepartment of Physics and Astronomy, Kokand State University, Kokand 713000, UzbekistanN. Z. MamadalievaDepartment of Physics and Astronomy, Kokand State University, Kokand 713000, UzbekistanShakhlo R. KukanbaevaDepartment of Physics and Astronomy, Kokand State University, Kokand 713000, Uzbekistan
Inorganicsjournal2025en
ABI

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In this paper, we investigate the optical absorption and luminescence spectra of rare-earth garnets activated by the terbium (Tb3+) ion, as well as their magneto-optical properties. Crystals of terbium gallium garnet (TbGaG) and terbium aluminum garnet (TbAlG) are considered. The focus is on the physical and optical properties and structural features of the energy levels of rare-earth ions in the crystal field of garnets. This work highlights the importance of studying intraconfigurational 4f-4f and interconfigurational 4f-5d transitions, as well as the influence of the crystal field on the magnetic and optical properties of materials. Integrated methods are used, including absorption spectroscopy, luminescence and magneto-optical studies, which allows us to obtain detailed information on the excited states of rare-earth ions. The experimental results show the presence of significant Zeeman shifts, as well as anisotropy of the absorption and luminescence spectra, depending on the orientation of the crystal lattice and the external magnetic field. This work contributes to our understanding of the mechanisms of light absorption and emission in rare-earth garnets, which may facilitate the development of new optoelectronic devices based on them.

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