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Synthesizing an Innovative Nanocomposite to Improve Polymer Gel Performance

Huijun QiDepartment of Materials Environmental Engineering Shanxi Polytechnic College Taiyuan Shanxi ChinaFarag M. A. AltalbawyDepartment of Chemistry, University College of Duba University of Tabuk Tabuk Saudi ArabiaTarak VoraMarwadi University Research Center, Department of Civil Engineering, Faculty of Engineering & Technology Marwadi University Rajkot Gujarat IndiaR. ManjunathaDepartment of Data Analytics and Mathematical Sciences, School of Sciences JAIN (Deemed‐to‐be University) Bangalore Karnataka IndiaRishabh ThakurCentre for Research Impact and Outcome, Chitkara University Institute of Engineering and Technology Chitkara University Rajpura Punjab IndiaB. AngelDepartment of Mathematics Sathyabama Institute of Science and Technology Chennai Tamil Nadu IndiaPriyadarshi DasDepartment of Civil Engineering Siksha “O” Anusandhan (Deemed to be University) Bhubaneswar Odisha IndiaAnup Singh NegiDepartment of Mathematics Graphic Era Hill University Dehradun Uttarakhand IndiaShoira FormanovaDepartment of Chemistry and Its Teaching Methods Tashkent State Pedagogical University Tashkent UzbekistanFadhil Faez SeadDepartment of Dentistry, College of Dentistry The Islamic University Najaf IraqAseel SmeratDepartment of Biosciences, Saveetha School of Engineering Saveetha Institute of Medical and Technical Sciences Chennai Tamil Nadu IndiaHojjat AbbasiDepartment of Chemistry Herat University Herat Afghanistan
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ABSTRACT In situ gel systems play a critical role in enhanced oil recovery (EOR) and water shutoff operations by improving fluid control in reservoirs and mitigating unwanted water production during extraction. However, challenges such as poor thermal stability and syneresis limit the performance of conventional gels. To overcome these issues, this study synthesizes and introduces an innovative TiO 2 @saponin/Zr(IV) nanocomposite to enhance gelation efficiency in polymer‐based gels. The nanocomposite was synthesized and characterized using FT‐IR spectroscopy, thermogravimetric analysis (TGA), and scanning electron microscopy (SEM), confirming its structural integrity, thermal stability, and nanoscale uniformity (particle size: 22–49 nm). Experimental results demonstrate significant improvements in gel performance due to the nanocomposite's incorporation. Syneresis tests showed that nanocomposite gels maintained structural integrity with only 8% water expulsion after 2 months under 105°C and 2000 psi, compared to 90% syneresis in nano‐free gels. Core flooding experiments highlighted the nanocomposite's impact on fluid control, achieving a residual resistance factor (RRF) of over 4000, far surpassing the RRF of < 50 for nano‐free gels. These findings underscore the efficacy of TiO 2 @saponin/Zr(IV) nanocomposites in enhancing polymer gels' mechanical and structural properties.

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