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Bright and Robust Phosphorescence Achieved by Non‐Covalent Clipping

Zi‐Jian LiCAS Key Laboratory of Soft Matter Chemistry Department of Polymer Science and Engineering University of Science and Technology of China Hefei Anhui 230026 P. R. ChinaYifei HanCAS Key Laboratory of Soft Matter Chemistry Department of Polymer Science and Engineering University of Science and Technology of China Hefei Anhui 230026 P. R. ChinaFude NieInstitute of Chemical Materials China Academy of Engineering Physics Mianyang 621900 P. R. ChinaMingyang LiuCAS Key Laboratory of Soft Matter Chemistry Department of Polymer Science and Engineering University of Science and Technology of China Hefei Anhui 230026 P. R. ChinaHua ZhongCAS Key Laboratory of Soft Matter Chemistry Department of Polymer Science and Engineering University of Science and Technology of China Hefei Anhui 230026 P. R. ChinaFeng WangCAS Key Laboratory of Soft Matter Chemistry Department of Polymer Science and Engineering University of Science and Technology of China Hefei Anhui 230026 P. R. China

2021en

ABI

Annotatsiya

Abstract Phosphorescent materials with bright emission in versatile media are important for their practical applications, which require to lower the susceptibility of triplet excitons to surroundings. Herein a non‐covalent clipping strategy has been developed to attain this objective, by designing a tweezer receptor to encapsulate Pt II ‐based triplet emitters through two‐fold π‐stacking interactions. The Pt II emitters display robust phosphorescence by virtue of synergistic rigidifying and shielding effects, which are hardly influenced by emitter concentration, oxygen content, and solvent polarity changes. The phosphorescent colors are elaborately modulated by varying ligand substitutes on Pt II emitters. Circularly polarized phosphorescence is further amplified for chiral Pt II emitters, by taking advantage of dual phosphorescence and chirality enhancement upon non‐covalent tweezer complexation. Overall, the clipping approach paves the way for the development of high‐performance phosphorescent materials with bright emission, environmental robustness, and facile color tunability.

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Identifikatorlar

DOI: 10.1002/anie.202015846

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