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Room temperature, template-free synthesis of BiOI hierarchical structures: Visible-light photocatalytic and electrochemical hydrogen storage properties

Yongqian LeiState Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, Jilin, ChinaGuanhua WangGraduate School of the Chinese Academy of Sciences, Beijing, P. R. ChinaShuyan SongGraduate School of the Chinese Academy of Sciences, Beijing, P. R. ChinaWeiqiang FanGraduate School of the Chinese Academy of Sciences, Beijing, P. R. ChinaMin PangGraduate School of the Chinese Academy of Sciences, Beijing, P. R. ChinaJinkui TangState Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin, ChinaHongjie ZhangState Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin, China

2010en

ABI

Annotatsiya

Three-dimensional (3D) flower-like BiOI hierarchical structures have been successfully synthesized by a solution route at room temperature. The obtained sample was systematically studied by powder X-ray diffraction (XRD), field-emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM). It is noteworthy that no surfactant or assisted reagent was needed during the formation of this uniform flower-like structure. It was proposed that primary nanoflakes of Bi-EtOH complexes were initially formed in the solution, and then anisotropic growth led to the development of 3D flowerlike structures. In addition, the photocatalytic property of the sample under visible-light was investigated with three types of dye: heteropolyaromatic (Methylene Blue (MB)), azoic (Methyl Orange (MO)) and phenol (rhodamine B (RhB)). High photocatalytic activity was observed for the phenol dye RhB. The electrochemical hydrogen storage properties were also investigated.

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Identifikatorlar

DOI: 10.1039/b922126c

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