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Biosorption of Trivalent Chromium on the Brown Seaweed Biomass

Yeoung‐Sang YunDepartment of Chemical Engineering, School of Environmental Science and Engineering, Pohang University of Science and Technology, San 31, Hyoja-dong, Pohang 790-784, Korea, and Department of Chemical Engineering, McGill University, 3610 University Street, Montreal, Quebec H3A 2B2, CanadaDonghee ParkDepartment of Chemical Engineering, School of Environmental Science and Engineering, Pohang University of Science and Technology, San 31, Hyoja-dong, Pohang 790-784, Korea, and Department of Chemical Engineering, McGill University, 3610 University Street, Montreal, Quebec H3A 2B2, CanadaJong Moon ParkDepartment of Chemical Engineering, School of Environmental Science and Engineering, Pohang University of Science and Technology, San 31, Hyoja-dong, Pohang 790-784, Korea, and Department of Chemical Engineering, McGill University, 3610 University Street, Montreal, Quebec H3A 2B2, CanadaBohumil VoleskyDepartment of Chemical Engineering, School of Environmental Science and Engineering, Pohang University of Science and Technology, San 31, Hyoja-dong, Pohang 790-784, Korea, and Department of Chemical Engineering, McGill University, 3610 University Street, Montreal, Quebec H3A 2B2, Canada

2001en

ABI

Annotatsiya

Biosorption has attracted attention as a cost-effective means for the treatment of metal-bearing wastewater. However, the mechanism of metal binding is not clearly understood, and consequently, modeling of the biosorption performance is still raising debates. In this study, the biosorption of trivalent chromium was investigated with protonated brown alga Ecklonia biomass as a model system. Titration of the biomass revealed that it contains at least three types of functional groups. The Fourier transform infrared spectrometry showed that the carboxyl group was the chromium-binding site within the pH range (pH 1-5) used in this study, where chromium does not precipitate. The pK value and the number of carboxyl groups were estimated to be 4.6 +/- 0.1 and 2.2 +/- 0.1 mmol/g, respectively. The equilibrium sorption isotherms determined at different solution pH indicated that the uptake of chromium increased significantly with increasing pH. A model for the description of chromium biosorption was developed incorporating the hydrolysis reactions that chromium undergoes in the aquatic phase. The model was able to predict the equilibrium sorption experimental data at different pH values and chromium concentrations. In addition, the speciation of the binding site as a function of the solution pH was predicted using the model in order to visualize the distribution of chromium ionic species on the binding site.

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Identifikatorlar

DOI: 10.1021/es010866k

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