High storage capacity and separation selectivity for C<sub>2</sub> hydrocarbons over methane in the metal–organic framework Cu–TDPAT
Kang LiuChangchun 130012, P. R. ChinaDingxuan MaChangchun 130012, P. R. ChinaBaiyan LiChangchun 130012, P. R. ChinaYi LiChangchun 130012, P. R. ChinaKexin YaoAdvanced Membranes and Porous Materials CenterZhijuan ZhangInstitute of Atmospheric Environment Safety and Pollution ControlYu HanAdvanced Membranes and Porous Materials CenterZhan ShiChangchun 130012, P. R. China
2014en
ABI
Annotatsiya
We report an <italic>rht</italic>-type metal–organic framework (MOF) which exhibits a high adsorption capacity for C<sub>2</sub> hydrocarbons and excellent selectivity over CH<sub>4</sub>. This MOF displays the highest reported C<sub>2</sub>H<sub>2</sub>–CH<sub>4</sub> selectivity of 127.1 as well as a record high value for C<sub>2</sub>H<sub>4</sub> adsorption enthalpy (49.5 kJ mol<sup>−1</sup>).
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