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Metal–organic framework materials as catalysts

Jeong‐Yong LeeDepartment of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208-3113, USAOmar K. FarhaDepartment of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, USAJohn M. RobertsDepartment of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, USAKarl A. ScheidtDepartment of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, USASonBinh T. NguyenDepartment of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, USAJoseph T. HuppDepartment of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, USA
2009en
ABI

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A critical review of the emerging field of MOF-based catalysis is presented. Discussed are examples of: (a) opportunistic catalysis with metal nodes, (b) designed catalysis with framework nodes, (c) catalysis by homogeneous catalysts incorporated as framework struts, (d) catalysis by MOF-encapsulated molecular species, (e) catalysis by metal-free organic struts or cavity modifiers, and (f) catalysis by MOF-encapsulated clusters (66 references).

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