Cation‐Exchange Porosity Tuning in Anionic Metal–Organic Frameworks for the Selective Separation of Gases and Vapors and for Catalysis
Elsa Quartapelle ProcopioDepartamento de Química Inorgánica, Universidad de Granada, Av. Fuentenueva S/N, 18071 Granada, SpainF. LinaresDepartamento de Química Inorgánica, Universidad de Granada, Av. Fuentenueva S/N, 18071 Granada (Spain),Carmen MontoroDepartamento de Química Inorgánica, Universidad de Granada, Av. Fuentenueva S/N, 18071 Granada (Spain),Valentina ColomboDipartimento di Scienze Chimiche e Ambientali, Università dell'Insubria, Via Valleggio 11, 22100 Como (Italy)Angelo MasperoDipartimento di Scienze Chimiche e Ambientali, Università dell'Insubria, Via Valleggio 11, 22100 Como (Italy)E. BareaDepartamento de Química Inorgánica, Universidad de Granada, Av. Fuentenueva S/N, 18071 Granada (Spain),Jorge A. R. NavarroDepartamento de Química Inorgánica, Universidad de Granada, Av. Fuentenueva S/N, 18071 Granada (Spain),
2010en
ABI
Annotatsiya
Temperature matters! The separation efficiency of complex mixtures of gases (acetylene, carbon dioxide, methane, nitrogen) and vapors (benzene, cyclohexane) by adsorption on A[Cu3(μ3-OH)(μ3-4-carboxypyrazolato)3] (A@1) metal–organic frameworks depends on temperature and the extraframework cation A (see picture). NH4@1 also behaves as an oxidation catalyst.
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