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Metal–Organic‐Framework‐Derived Hollow N‐Doped Porous Carbon with Ultrahigh Concentrations of Single Zn Atoms for Efficient Carbon Dioxide Conversion

Qihao YangHefei National Laboratory for Physical Sciences at the Microscale CAS Key Laboratory of Soft Matter Chemistry Collaborative Innovation Center of Suzhou Nano Science and Technology Department of Chemistry University of Science and Technology of China Hefei Anhui 230026 P. R. ChinaChun‐Chuen YangDepartment of Chemistry Chung Yuan Christian University Taoyuan 32023 TaiwanChia‐Her LinDepartment of Chemistry Chung Yuan Christian University Taoyuan 32023 TaiwanHai‐Long JiangHefei National Laboratory for Physical Sciences at the Microscale CAS Key Laboratory of Soft Matter Chemistry Collaborative Innovation Center of Suzhou Nano Science and Technology Department of Chemistry University of Science and Technology of China Hefei Anhui 230026 P. R. China

2018en

ABI

Annotatsiya

Abstract The development of efficient and low energy‐consumption catalysts for CO 2 conversion is desired, yet remains a great challenge. Herein, a class of novel hollow porous carbons (HPC), featuring well dispersed dopants of nitrogen and single Zn atoms, have been fabricated, based on the templated growth of a hollow metal–organic framework precursor, followed by pyrolysis. The optimized HPC‐800 achieves efficient catalytic CO 2 cycloaddition with epoxides, under light irradiation, at ambient temperature, by taking advantage of an ultrahigh loading of (11.3 wt %) single‐atom Zn and uniform N active sites, high‐efficiency photothermal conversion as well as the hierarchical pores in the carbon shell. As far as we know, this is the first report on the integration of the photothermal effect of carbon‐based materials with single metal atoms for catalytic CO 2 fixation.

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Identifikatorlar

DOI: 10.1002/anie.201813494

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