Regulating the *OCCHO intermediate pathway towards highly selective photocatalytic CO<sub>2</sub> reduction to CH<sub>3</sub>CHO over locally crystallized carbon nitride
Qiong LiuInstitute of Analysis, Guangdong Academy of Sciences (China National Analytical Center, Guangzhou), Guangzhou, Guangdong, 510070, ChinaHui ChengInstitute of Analysis, Guangdong Academy of Sciences (China National Analytical Center, Guangzhou), Guangzhou, Guangdong, 510070, ChinaTianxiang ChenState Key Laboratory of Chemical Biology and Drug Discovery, Department of Applied Biology and Chemical Technology, The Hong Kong Polytechnic University, Hong Kong, ChinaTsz Woon Benedict LoState Key Laboratory of Chemical Biology and Drug Discovery, Department of Applied Biology and Chemical Technology, The Hong Kong Polytechnic University, Hong Kong, ChinaZhangmin XiangInstitute of Analysis, Guangdong Academy of Sciences (China National Analytical Center, Guangzhou), Guangzhou, Guangdong, 510070, ChinaFuxian WangInstitute of Analysis, Guangdong Academy of Sciences (China National Analytical Center, Guangzhou), Guangzhou, Guangdong, 510070, China
2021en
ABI
Annotatsiya
Locally crystallized PCN is prone to form *OCCHO groups rather than *CH 2 O groups, regulating the endoergic C–C coupling step to a simultaneous exoergic reaction and changing the reaction pathway towards CH 3 CHO (selectivity of 98.3%) instead of HCHO.
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