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An all-sputtered photovoltaic ultraviolet photodetector based on co-doped CuCrO2 and Al-doped ZnO heterojunction

Morteza AhmadiLaser and Plasma Research Institute, Shahid Beheshti University, Tehran, IranMasoud AbrariLaser and Plasma Research Institute, Shahid Beheshti University, Tehran, IranMajid GhanaatshoarLaser and Plasma Research Institute, Shahid Beheshti University, Tehran, Iran. [email protected]
2021en
ABI

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Abstract We propose and fabricate a heterojunction between Al-doped ZnO and (Mg, N)-doped CuCrO 2 thin films using the sputtering deposition method. These materials possess wide bandgap that makes them transparent in the visible light but excellent UV-absorbers. On the other hand, the high conductivity of these materials, respectively as n-type and p-type transparent conducting oxides, facilitates the charge transport. We show that the p–n junction fabricated from these materials has the potential to act as a high-performance UV photovoltaic photodetector. The proposed structure, demonstrates fast responses in order of sub seconds, photosensitivity of ~ 41,000, responsivity of 1.645 mA/W, and a detectivity of 3.52 × 10 12 Jones that are significantly improved in comparison with the Al-doped ZnO photoconductor. This excellent improvement is attributed to the capability of the photovoltaic configuration that creates a built-in voltage and facilitates the charge separation and collection rather than recombination in the photoconductor configuration.

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