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Cationic surface functionalization of cellulose nanocrystals

Merima HasaniDepartment of Chemical and Biological Engineering, Chalmers University of Technology, Göteborg, SwedenEmily D. CranstonDepartment of Chemistry, Pulp and Paper Research Center, McGill University, Montréal, Québec, CanadaGunnar WestmanDepartment of Chemical and Biological Engineering, Chalmers University of Technology, Göteborg, SwedenDerek G. GrayDepartment of Chemistry, Pulp and Paper Research Center, McGill University, Montréal, Québec, Canada

2008en

ABI

Annotatsiya

The surface of cellulose nanocrystals, prepared by sulfuric acid hydrolysis of cotton, was rendered cationic through a reaction with epoxypropyltrimethylammonium chloride. The resultant nanocrystal suspensions were characterized by ζ-potential, conductometric titration and polarized light microscopy. Atomic force microscopy (AFM) showed no change in the size or shape of the nanocrystals, but the functionalization process reversed the surface charge and led to a reduction of the total surface charge density. These modifications led to stable aqueous suspensions of nanocrystalline cellulose with unexpected gelling and rheological properties. Shear birefringence was observed, but no liquid crystalline chiral nematic phase separation was detected.

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DOI: 10.1039/b806789a

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