<title>Raman study of molecular associations in methanol</title>
Л. А. БулавінTaras Shevchenko National Univ. of Kyiv (Ukraine)I. DoroshenkoTaras Shevchenko National Univ. of Kyiv (Ukraine)Olexandr I. LizengevichTaras Shevchenko National Univ. of Kyiv (Ukraine)Valerii E. PogorelovTaras Shevchenko National Univ. of Kyiv (Ukraine)L.I. SavranskyTaras Shevchenko National Univ. of Kyiv (Ukraine)O. VeretennikovTaras Shevchenko National Univ. of Kyiv (Ukraine)
2004en
ABI
Annotatsiya
Raman spectra of liquid methanol were registered in wide temperature range (150 - 340 K) at different rates of temperature changing for the frequency region 950 - 3700 cm<sup>-1</sup>. Quantum chemical calculations of parameters of vibrational spectra of free molecule and of some associates were made. Comparison of these results and experimental data allows to insist that there are no monomers and dimers in liquid methanol. The only stable form is cyclic clusters. The widths ofthe bands do not depend on temperature and this fact indicates the stability of methanol structure in condensed state.
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