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Ti<sub>2</sub>Au<sub>2</sub>C and Ti<sub>3</sub>Au<sub>2</sub>C<sub>2</sub> formed by solid state reaction of gold with Ti<sub>2</sub>AlC and Ti<sub>3</sub>AlC<sub>2</sub>

Hossein FashandiChemistry, and Biology (IFM)Chung‐Chuan LaiChemistry, and Biology (IFM)Martin DahlqvistChemistry, and Biology (IFM)Jun LuChemistry, and Biology (IFM)Johanna RosénChemistry, and Biology (IFM)Lars HultmanChemistry, and Biology (IFM)Grzegorz GreczyńskiChemistry, and Biology (IFM)Mike AnderssonChemistry, and Biology (IFM)Anita Lloyd SpetzChemistry, and Biology (IFM)Per EklundChemistry, and Biology (IFM)
2017en
ABI

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and determine their structures by electron microscopy, X-ray diffraction, and ab initio calculations. These results imply that noble-metal-containing layered phases should be possible to synthesize in many systems. The metal to be introduced should be inert to the transition-metal carbide layers, and exhibit negative heat of mixing with the initial A element in a liquid phase or two-phase liquid/solid region at the annealing temperature.

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