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Engineering the Electrical Conductivity of Lamellar Silver‐Doped Cobalt(II) Selenide Nanobelts for Enhanced Oxygen Evolution

Xu ZhaoHefei National Laboratory for Physical Sciences at the Microscale Key Laboratory of Strongly-Coupled Quantum Matter Physics of Chinese Academy of Sciences Hefei Science Center National Synchrotron Radiation Laboratory Department of Chemical Physics University of Science and Technology of China Hefei, Anhui 230026 P.R. ChinaHantao ZhangHefei National Laboratory for Physical Sciences at the Microscale Key Laboratory of Strongly-Coupled Quantum Matter Physics of Chinese Academy of Sciences Hefei Science Center National Synchrotron Radiation Laboratory Department of Chemical Physics University of Science and Technology of China Hefei, Anhui 230026 P.R. ChinaYu YanHefei National Laboratory for Physical Sciences at the Microscale Key Laboratory of Strongly-Coupled Quantum Matter Physics of Chinese Academy of Sciences Hefei Science Center National Synchrotron Radiation Laboratory Department of Chemical Physics University of Science and Technology of China Hefei, Anhui 230026 P.R. ChinaJinhua CaoHefei National Laboratory for Physical Sciences at the Microscale Key Laboratory of Strongly-Coupled Quantum Matter Physics of Chinese Academy of Sciences Hefei Science Center National Synchrotron Radiation Laboratory Department of Chemical Physics University of Science and Technology of China Hefei, Anhui 230026 P.R. ChinaXingqi LiHefei National Laboratory for Physical Sciences at the Microscale Key Laboratory of Strongly-Coupled Quantum Matter Physics of Chinese Academy of Sciences Hefei Science Center National Synchrotron Radiation Laboratory Department of Chemical Physics University of Science and Technology of China Hefei, Anhui 230026 P.R. ChinaShiming ZhouHefei National Laboratory for Physical Sciences at the Microscale Key Laboratory of Strongly-Coupled Quantum Matter Physics of Chinese Academy of Sciences Hefei Science Center National Synchrotron Radiation Laboratory Department of Chemical Physics University of Science and Technology of China Hefei, Anhui 230026 P.R. ChinaZhenmeng PengDepartment of Chemical and Biomolecular Engineering University of Akron Akron OH 44325 USAJie ZengHefei National Laboratory for Physical Sciences at the Microscale Key Laboratory of Strongly-Coupled Quantum Matter Physics of Chinese Academy of Sciences Hefei Science Center National Synchrotron Radiation Laboratory Department of Chemical Physics University of Science and Technology of China Hefei, Anhui 230026 P.R. China

2016en

ABI

Annotatsiya

Abstract Precisely engineering the electrical conductivity represents a promising strategy to design efficient catalysts towards oxygen evolution reaction (OER). Here, we demonstrate a versatile partial cation exchange method to fabricate lamellar Ag‐CoSe 2 nanobelts with controllable conductivity. The electrical conductivity of the materials was significantly enhanced by the addition of Ag + cations of less than 1.0 %. Moreover, such a trace amount of Ag induced a negligible loss of active sites which was compensated through the effective generation of active sites as shown by the excellent conductivity. Both the enhanced conductivity and the retained active sites contributed to the remarkable electrocatalytic performance of the Ag‐CoSe 2 nanobelts. Relative to the CoSe 2 nanobelts, the as‐prepared Ag‐CoSe 2 nanobelts exhibited a higher current density and a lower Tafel slope towards OER. This strategy represents a rational design of efficient electrocatalysts through finely tuning their electrical conductivities.

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Identifikatorlar

DOI: 10.1002/ange.201609080

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