Electroceramics: Characterization by Impedance Spectroscopy
John T. S. IrvineDepartment of Chemistry, University of Aberdeen Meston Building, Meston Walk, Old Aberdeen AB9 2UE (Scotland)Derek C. SinclairDepartment of Chemistry, University of Aberdeen Meston Building, Meston Walk, Old Aberdeen AB9 2UE (Scotland)Anthony R. WestDepartment of Chemistry, University of Aberdeen Meston Building, Meston Walk, Old Aberdeen AB9 2UE (Scotland)
1990en
ABI
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Abstract Electroceramics are advanced materials whose properties and applications depend on the close control of structure, composition, ceramic texture, dopants and dopant (or defect) distribution. Impedance spectroscopy is a powerful technique for unravelling the complexities of such materials, which functions by utilizing the different frequency dependences of the constituent components for their separation. Thus, electrical inhomogeneities in ceramic electrolytes, electrode/electrolyte interfaces, surface layers on glasses, ferroelectricity, positive temperature coefficient of resistance behavior and even ferrimagnetism can all be probed, successfully, using this technique.
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