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The two-dimensional phase of boron nitride: Few-atomic-layer sheets and suspended membranes

D. PacilèLawrence Berkeley National Laboratory 2 Materials Sciences Division, , Berkeley, California 94720, USAJannik C. MeyerLawrence Berkeley National Laboratory 2 Materials Sciences Division, , Berkeley, California 94720, USAÇağlar GiritLawrence Berkeley National Laboratory 2 Materials Sciences Division, , Berkeley, California 94720, USAAlex ZettlLawrence Berkeley National Laboratory 2 Materials Sciences Division, , Berkeley, California 94720, USA
2008en
ABI

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We describe the synthesis of very thin sheets (between a few and ten atomic layers) of hexagonal boron nitride (h-BN), prepared either on a SiO2 substrate or freely suspended. Optical microscopy, atomic force microscopy, and transmission electron microscopy have been used to characterize the morphology of the samples and to distinguish between regions of different thicknesses. Comparison is made to previous studies on single- and few-layer graphene. This synthesis opens the door to experimentally accessing the two-dimensional phase of boron nitride.

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