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Critical Review of rate constants for reactions of hydrated electrons, hydrogen atoms and hydroxyl radicals (⋅OH/⋅O− in Aqueous Solution

George V. BuxtonUniversity of Leeds, Cookridge Radiation Research Centre, Leeds, LS16 6QB, EnglandC.L. GreenstockMedical Biophysics Branch, Whiteshell Nuclear Research Establishment, Atomic Energy of Canada Limited Research Company, Pinawa, Maitoba, Canada, ROE 1LOW. Phillips HelmanRadiation Chemistry Data Center, Radiation Laboratory, University of Notre Dame, Indiana 46556Alberta B. RossRadiation Chemistry Data Center, Radiation Laboratory, University of Notre Dame, Indiana 46556
1988en
ABI

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Kinetic data for the radicals H⋅ and ⋅OH in aqueous solution,and the corresponding radical anions, ⋅O− and eaq−, have been critically pulse radiolysis, flash photolysis and other methods. Rate constants for over 3500 reaction are tabulated, including reaction with molecules, ions and other radicals derived from inorganic and organic solutes.

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