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Phosphorus acceptor doped ZnO nanowires prepared by pulsed-laser deposition

Bingqiang CaoInstitut für Experimentelle Physik II, Universität Leipzig, Linnéstraße 5, D-04103Leipzig, GermanyMichael LorenzInstitut für Experimentelle Physik II, Universität Leipzig, Linnéstraße 5, D-04103Leipzig, GermanyA. RahmInstitut für Experimentelle Physik II, Universität Leipzig, Linnéstraße 5, D-04103Leipzig, GermanyHolger von WencksternInstitut für Experimentelle Physik II, Universität Leipzig, Linnéstraße 5, D-04103Leipzig, GermanyC. CzekallaInstitut für Experimentelle Physik II, Universität Leipzig, Linnéstraße 5, D-04103Leipzig, GermanyJ. LenznerInstitut für Experimentelle Physik II, Universität Leipzig, Linnéstraße 5, D-04103Leipzig, GermanyG. BenndorfInstitut für Experimentelle Physik II, Universität Leipzig, Linnéstraße 5, D-04103Leipzig, GermanyMarius GrundmannInstitut für Experimentelle Physik II, Universität Leipzig, Linnéstraße 5, D-04103Leipzig, Germany
2007en
ABI

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Phosphorus-doped ZnO (ZnO:P) nanowires were successfully prepared by a novel high-pressure pulsed-laser deposition process using phosphorus pentoxide as the dopant source. Detailed cathodoluminescence studies of single ZnO:P nanowires revealed characteristic phosphorus acceptor-related peaks: neutral acceptor-bound exciton emission (A0, X, 3.356 eV), free-to-neutral-acceptor emission (e, A0, 3.314 eV), and donor-to-acceptor pair emission (DAP, ∼3.24 and ∼3.04 eV). This means that stable acceptor levels with a binding energy of about 122 meV have been induced in the nanowires by phosphorus doping. Moreover, the induced acceptors are distributed homogeneously along the doped nanowires.

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