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Nonlinear Optical Response of Organic–Inorganic Halide Perovskites

Rui ZhangState Key Laboratory of Crystal Materials and Institute of Crystal Materials, Shandong University, Jinan 250100, ChinaJiandong FanClarendon Laboratory, University of Oxford, Parks Road, Oxford OX1 3PU, United KingdomXing ZhangInstitute of Photovoltaics, College of Physics Science and Technology, Hebei University, Baoding 071002, ChinaHaohai YuState Key Laboratory of Crystal Materials and Institute of Crystal Materials, Shandong University, Jinan 250100, ChinaHuaijin ZhangState Key Laboratory of Crystal Materials and Institute of Crystal Materials, Shandong University, Jinan 250100, ChinaYaohua MaiInstitute of Photovoltaics, College of Physics Science and Technology, Hebei University, Baoding 071002, ChinaTianxiang XuState Key Laboratory of Crystal Materials and Institute of Crystal Materials, Shandong University, Jinan 250100, ChinaJiyang WangState Key Laboratory of Crystal Materials and Institute of Crystal Materials, Shandong University, Jinan 250100, ChinaHenry J. SnaithClarendon Laboratory, University of Oxford, Parks Road, Oxford OX1 3PU, United Kingdom

2016en

ABI

Annotatsiya

Metal halide perovskites have exhibited excellent properties as absorbers in solar cells, but this may simply be the first of many applications for this intriguing class of materials. Here, we report the nonlinear optical response of triiodide (CH3NH3PbI3) and mixed halide (CH3NH3PbI3–xClx) perovskite absorbers. The results show that they have large nonlinear refractive index (NRI), 3 orders of magnitude larger than that of silicon. Particularly, the NRI of CH3NH3PbI3–xClx is more than two times larger compared to that of CH3NH3PbI3. Meanwhile, both of them have been proven to possess saturable absorption effects with small nonlinear absorption coefficients which indicate that they can maintain excellent absorption under high-intensity irradiation and are favorable to modulators toward large-energy pulsed laser. Taking into consideration the saturable absorption effect, we demonstrated a pulsed laser with the perovskite as a pulse modulator. These results above indicate the potential for perovskites to be employed in nonlinear optoelectronic devices.

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DOI: 10.1021/acsphotonics.5b00563

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