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Magnetite: Phonon modes and the Verwey transition

L. DegiorgiLaboratorium für Festkörperphysik, Eidgenössische Technische Hochschule Zürich, 8093 Zürich, SwitzerlandI. Blatter-MörkeLaboratorium für Festkörperphysik, Eidgenössische Technische Hochschule Zürich, 8093 Zürich, SwitzerlandP. WächterLaboratorium für Festkörperphysik, Eidgenössische Technische Hochschule Zürich, 8093 Zürich, Switzerland
1987en
ABI

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Reflectivity and Raman measurements of magnetite at 300, 130, 80, and 6 K are presented. The four infrared-active phonon modes and the five Raman modes exhibit fine structures below the Verwey transition (120 K), which are clearly detected for what may be the first time. A phenomenological analysis of the phonon spectrum at 130 K is performed.

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