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Monodisperse Porous LiFePO<sub>4</sub> Microspheres for a High Power Li-Ion Battery Cathode

Chunwen SunTexas Materials Institute, ETC 9.184, University of Texas at Austin, Austin, Texas 78712, United StatesShreyas RajasekharaTexas Materials Institute, ETC 9.184, University of Texas at Austin, Austin, Texas 78712, United StatesJohn B. GoodenoughTexas Materials Institute, ETC 9.184, University of Texas at Austin, Austin, Texas 78712, United StatesFeng ZhouTexas Materials Institute, ETC 9.184, University of Texas at Austin, Austin, Texas 78712, United States
2011en
ABI

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A novel solvothermal approach combined with high-temperature calcinations was developed to synthesize on a large scale LiFePO(4) microspheres consisting of nanoplates or nanoparticles with an open three-dimensional (3D) porous microstructure. These micro/nanostructured LiFePO(4) microspheres have a high tap density and, as electrodes, show excellent rate capability and cycle stability.

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