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Occurrence of n-Alkanes in Vegetable Oils and Their Analytical Determination

Ana SrbinovskaDepartment of Agri-Food, Environmental and Animal Sciences, University of Udine, 33100 Udine, ItalyChiara ConchioneDepartment of Agri-Food, Environmental and Animal Sciences, University of Udine, 33100 Udine, ItalyLuca Menegoz UrsolDepartment of Agri-Food, Environmental and Animal Sciences, University of Udine, 33100 Udine, ItalyPaolo LucciDepartment of Agri-Food, Environmental and Animal Sciences, University of Udine, 33100 Udine, ItalySabrina MoretDepartment of Agri-Food, Environmental and Animal Sciences, University of Udine, 33100 Udine, Italy
2020en
ABI

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Vegetable oils contain endogenous linear hydrocarbons, namely n-alkanes, ranging from n-C21 to n-C35, with odd chain lengths prevalent. Different vegetable oils, as well as oils of the same type, but of different variety and provenience, show typical n-alkane patterns, which could be used as a fingerprint to characterize them. In the first part of this review, data on the occurrence of n-alkanes in different vegetable oils (total and predominant n-alkanes) are given, with a focus on obtaining information regarding variety and geographical origin. The second part aims to provide the state of the art on available analytical methods for their determination. In particular, a detailed description of the sample preparation protocols and analytical determination is reported, pointing out the main drawbacks of traditional sample preparation and possible solutions to implement the analysis with the aim to shift toward rapid and solvent-sparing methods.

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