Ag<sub>3</sub>O<sub>4</sub>, the First Silver(<scp>II,III</scp>) Oxide
Burkhard StandkeInstitut für Anorganische Chemie der Universität, Callinstrasse 9, D‐3000 Hannover 1 (FRG)Martin JansenInstitut für Anorganische Chemie der Universität, Callinstrasse 9, D-3000 Hannover 1 (FRG)
1986en
ABI
Annotatsiya
The silver oxide Ag 3 O 4 contains crystallographically differentiable di‐ and trivalent silver ions, each in square‐planar oxygen environment. From the bond lengths it is concluded that extensive charge equalization takes place between Ag 2+ and Ag 3+ , Ag 3 O 4 is obtained by anodic oxidation of silver salt solutions.
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