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The Effect of N‐Containing Supports on Catalytic CO Oxidation Activity over Highly Dispersed Pt/UiO‐67

Gui‐Lin ZhuangCollege of Chemical Engineering Zhejiang University of Technology 310032 Hangzhou P.R. ChinaJia‐qi BaiCollege of Chemical Engineering Zhejiang University of Technology 310032 Hangzhou P.R. ChinaXiang ZhouCollege of Chemical Engineering Zhejiang University of Technology 310032 Hangzhou P.R. ChinaYi-Fen GaoCollege of Chemical Engineering Zhejiang University of Technology 310032 Hangzhou P.R. ChinaHongliang HuangBeijing University of Chemical Technology State Key Laboratory of OrganicInorganic Composites 100029 Beijing P.R. ChinaHai‐quan CuiCollege of Chemical Engineering Zhejiang University of Technology 310032 Hangzhou P.R. ChinaXing ZhongCollege of Chemical Engineering Zhejiang University of Technology 310032 Hangzhou P.R. ChinaChongli ZhongBeijing University of Chemical Technology State Key Laboratory of OrganicInorganic Composites 100029 Beijing P.R. ChinaJianguo WangCollege of Chemical Engineering Zhejiang University of Technology 310032 Hangzhou P.R. China

2016en

ABI

Annotatsiya

Investigations of the effects of the support on catalytic properties are important for heterogeneous systems. Herein, we report the preparation of highly dispersed Pt nanoparticles (NPs) in three isomorphous UiO‐67‐type metal–organic frameworks (MOFs), namely, pristine UiO‐67, N‐UiO‐67, and NH 2 ‐UiO‐67. Structural measurements revealed that the sizes of the Pt NPs were 4.5 nm for Pt/UiO‐67 and 2.5 nm for N‐UiO‐67 and NH 2 ‐UiO‐67. The dominant influences on the sizes of the Pt NPs are the functional groups of the support and the pore size of the MOF. Furthermore, CO catalytic oxidations were performed as a model reaction. Interestingly, the catalytic performance sequence is 5 % Pt/N‐UiO‐67 > 5 % Pt/UiO‐67 > 5 % Pt/NH 2 ‐UiO‐67. A combination of experimental measurement and DFT calculation revealed that the catalytic properties depend on not only the size of the Pt NPs but also the nature of the support.

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Identifikatorlar

DOI: 10.1002/ejic.201600867

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