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Enantioselective Hydrogenation of α‐Substituted Acrylic Acids Catalyzed by Iridium Complexes with Chiral Spiro Aminophosphine Ligands

Shou‐Fei ZhuState Key Laboratory and Institute of Elemento-organic Chemistry, Nankai University, Tianjin 300071 (China) http://zhou.nankai.edu.cn/Yanbo YuState Key Laboratory and Institute of Elemento-organic Chemistry, Nankai University, Tianjin 300071 (China) http://zhou.nankai.edu.cn/Shen LiState Key Laboratory and Institute of Elemento-organic Chemistry, Nankai University, Tianjin 300071 (China) http://zhou.nankai.edu.cn/Li‐Xin WangState Key Laboratory and Institute of Elemento-organic Chemistry, Nankai University, Tianjin 300071 (China) http://zhou.nankai.edu.cn/Qi‐Lin ZhouState Key Laboratory and Institute of Elemento-organic Chemistry, Nankai University, Tianjin 300071 (China) http://zhou.nankai.edu.cn/

2012en

ABI

Annotatsiya

Hoch aktiv: Iridium-Komplexe mit chiralen Spiro-Aminophosphanliganden wurden synthetisiert und als Katalysatoren für die asymmetrische Hydrierung von α-substituierten Acrylsäuren eingesetzt (siehe Schema). Die Komplexe waren hochaktive Katalysatoren mit Umsatzfrequenzen bis 6000 h−1, und die Katalysatormenge konnte auf 0.01 Mol-% gesenkt werden. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.

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Identifikatorlar

DOI: 10.1002/ange.201204363

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