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Palladium catalyzed Heck-Mizoroki and Suzuki-Miyaura coupling reactions (Review)

Muhammad Nadeem ZafarDepartment of Chemistry, Institute of Chemical and Biological Sciences (ICBS), University of Gujrat, Gujrat, 50700, PakistanMuhammad Ali MohsinDepartment of Chemistry, Institute of Chemical and Biological Sciences (ICBS), University of Gujrat, Gujrat, 50700, PakistanMuhammad DanishDepartment of Chemistry, Institute of Chemical and Biological Sciences (ICBS), University of Gujrat, Gujrat, 50700, PakistanMuhammad Faizan NazarDepartment of Chemistry, Institute of Chemical and Biological Sciences (ICBS), University of Gujrat, Gujrat, 50700, PakistanShahzad MurtazaDepartment of Chemistry, Institute of Chemical and Biological Sciences (ICBS), University of Gujrat, Gujrat, 50700, Pakistan

2014en

ABI

Annotatsiya

This article is about the progress of palladium compounds as a catalyst for Heck-Mizoroki and Suzuki-Miyaura coupling reactions. Industrial catalysts with broad applicability need continuous catalyst development process through modification of ligand design, geometry and functionality. Recently catalysts have been synthesized through attachment of the activated palladium complexes on the surface of polymer support, particularly, insoluble in reaction medium. An appropriate mixture of palladium salt and ligand is also used as an important modification in some cases to get better results. We surveyed the important palladium compounds synthesized up to early 2014 for Heck-Mizoroki and Suzuki-Miyaura coupling reactions and summarize their progress in terms of ligand modification and other associated parameters.

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DOI: 10.1134/s1070328414110104

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