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Advances on the Merger of Electrochemistry and Transition Metal Catalysis for Organic Synthesis

Christian A. MalapitDepartment of Chemistry, University of Utah, 315 South 1400 East, Salt Lake City, Utah 84112, United StatesMatthew B. PraterDepartment of Chemistry, University of Utah, 315 South 1400 East, Salt Lake City, Utah 84112, United StatesJaime R. Cabrera‐PardoDepartment of Chemistry, University of Utah, 315 South 1400 East, Salt Lake City, Utah 84112, United StatesMin LiDepartment of Chemistry, University of Utah, 315 South 1400 East, Salt Lake City, Utah 84112, United StatesTammy Dung PhamDepartment of Chemistry, University of Utah, 315 South 1400 East, Salt Lake City, Utah 84112, United StatesTimothy Patrick McFaddenDepartment of Chemistry, University of Utah, 315 South 1400 East, Salt Lake City, Utah 84112, United StatesSkylar BlankDepartment of Chemistry, University of Utah, 315 South 1400 East, Salt Lake City, Utah 84112, United StatesShelley D. MinteerDepartment of Chemistry, University of Utah, 315 South 1400 East, Salt Lake City, Utah 84112, United States

2021en

ABI

Annotatsiya

Synthetic organic electrosynthesis has grown in the past few decades by achieving many valuable transformations for synthetic chemists. Although electrocatalysis has been popular for improving selectivity and efficiency in a wide variety of energy-related applications, in the last two decades, there has been much interest in electrocatalysis to develop conceptually novel transformations, selective functionalization, and sustainable reactions. This review discusses recent advances in the combination of electrochemistry and homogeneous transition-metal catalysis for organic synthesis. The enabling transformations, synthetic applications, and mechanistic studies are presented alongside advantages as well as future directions to address the challenges of metal-catalyzed electrosynthesis.

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Identifikatorlar

DOI: 10.1021/acs.chemrev.1c00614

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