A Ligand-Directed Catalytic Regioselective Hydrocarboxylation of Aryl Olefins with Pd and Formic Acid
Wei LiuState
Key Laboratory of Coordination Chemistry, Collaborative Innovation
Center of Chemistry for Life Sciences, Center for Multimolecular Organic
Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, ChinaWenlong RenState
Key Laboratory of Coordination Chemistry, Collaborative Innovation
Center of Chemistry for Life Sciences, Center for Multimolecular Organic
Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, ChinaJingfu LiState
Key Laboratory of Coordination Chemistry, Collaborative Innovation
Center of Chemistry for Life Sciences, Center for Multimolecular Organic
Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, ChinaYuan ShiDepartment
of Chemistry, Colorado State University, Fort Collins, Colorado 80523, United StatesWenju ChangState
Key Laboratory of Coordination Chemistry, Collaborative Innovation
Center of Chemistry for Life Sciences, Center for Multimolecular Organic
Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, ChinaYian ShiDepartment
of Chemistry, Colorado State University, Fort Collins, Colorado 80523, United States
2017en
ABI
Annotatsiya
An effective Pd-catalyzed hydrocarboxylation of aryl olefins with Ac2O and formic acid is described. A variety of 2- and 3-arylpropanoic acids can be regioselectively formed by the judicious choice of ligand without the use of toxic CO gas.
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