Copper‐Catalyzed Cyanation of Aryl Iodides with Malononitrile: An Unusual Cyano Group Transfer Process from C(<i>sp</i><sup>3</sup>) to C(<i>sp</i><sup>2</sup>)
Zhaoqiong JiangInstitute of Homogeneous Catalysis, College of Chemistry, Sichuan University, Chengdu 610064, People's Republic of China,Qing HuangInstitute of Homogeneous Catalysis, College of Chemistry, Sichuan University, Chengdu 610064, People's Republic of China,Si ChenInstitute of Homogeneous Catalysis, College of Chemistry, Sichuan University, Chengdu 610064, People's Republic of China,La‐Sheng LongState Key Laboratory of Physical Chemistry of Solid Surface, Xiamen University, Xiamen 361005, People's Republic of ChinaXiangge ZhouInstitute of Homogeneous Catalysis, College of Chemistry, Sichuan University, Chengdu 610064, People's Republic of China,
2012en
ABI
Annotatsiya
Abstract An unusual copper‐catalyzed cyanation of aryl iodides to form aryl nitriles by cyano group transfer from C( sp 3 ) to C( sp 2 ) carbon atoms is reported and proceeds to give yields of up to 86%.
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